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Cleaning Laboratory Glassware

Why Clean Glassware?
For several reasons it is important that all glassware be cleaned properly before use.

  • Clean glassware is essential because small amounts of impurities left on the glassware from previous experiments can ruin the next experiment by inhibiting chemical reactions, catalyzing undesirable side reactions, or invalidating results of chemical tests.
  • Also, impurities or residues left on glassware can ruin it by attacking the glass, weakening its structure, and may lead to accidental breakage during future use.
How to Clean Glassware
The following procedures are recommended for the cleaning of general purpose glassware.
  • Always check your glassware for damage before using it. Remember, scratched or cracked glassware may not be safe to use. Small cracks are likely to expand during the application of heat to the glassware, causing it to shatter.
  • Most glassware can be adequately cleaned with water and soap solution by vigorous scrubbing (taking care not to scratch it) using a brush of appropriate size and shape. Some organic residues will not come off with soap solution and water but will dissolve in other solvents such as acetone or methylene chloride followed by a wash with soap solution and water. Your laboratory instructor will specify when solvents other than water are to be used for cleaning purposes.
  • After washing, always rinse the glassware thoroughly with tap water. Finally, rinse with several small portions of distilled water from a wash bottle. Usually, three, ten- milliliter portions of distilled water are sufficient. Rinsing your glassware with small amounts of distilled water is necessary to remove impurities contained in the tap water. Distilled water is expensive to produce and should be used sparingly when rinsing glassware.

Checking for Cleanliness
Check your glassware to see if it has been cleaned correctly. If glassware has been thoroughly cleaned, water applied to its inner surface should wet the whole surface evenly with no formation of droplets or dry patches. If this is not the case, rewash your glassware until it is clean. Contact your laboratory instructor if glassware does not come clean in spite of your best efforts.


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